A unique method for highly enantioselective synthesis of N–C axially chiral compounds

Osamu Kitagawa

doi:10.1016/j.chempr.2021.06.001

A unique method for highly enantioselective synthesis of N–C axially chiral compounds

Osamu Kitagawa

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In this issue of Chem, Zhou and co-workers report a new strategy for synthesizing optically active N–C axially chiral compounds. In the presence of a chiral norbornene-ester-Pd catalyst, the Catellani reaction of iodobenzene derivatives with N-(2-substituted-phenyl)-2-bromobenzamides proceeds in a highly enantioselective manner to give N–C axially chiral N-aryl-phenanthridinone derivatives.

Original language	English
Pages (from-to)	1696-1698
Number of pages	3
Journal	Chem
Volume	7
Issue number	7
DOIs	https://doi.org/10.1016/j.chempr.2021.06.001
Publication status	Published - 2021 Jul 8

ASJC Scopus subject areas

Chemistry(all)
Biochemistry
Environmental Chemistry
Chemical Engineering(all)
Biochemistry, medical
Materials Chemistry

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10.1016/j.chempr.2021.06.001

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title = "A unique method for highly enantioselective synthesis of N–C axially chiral compounds",

abstract = "In this issue of Chem, Zhou and co-workers report a new strategy for synthesizing optically active N–C axially chiral compounds. In the presence of a chiral norbornene-ester-Pd catalyst, the Catellani reaction of iodobenzene derivatives with N-(2-substituted-phenyl)-2-bromobenzamides proceeds in a highly enantioselective manner to give N–C axially chiral N-aryl-phenanthridinone derivatives.",

author = "Osamu Kitagawa",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Inc.",

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AB - In this issue of Chem, Zhou and co-workers report a new strategy for synthesizing optically active N–C axially chiral compounds. In the presence of a chiral norbornene-ester-Pd catalyst, the Catellani reaction of iodobenzene derivatives with N-(2-substituted-phenyl)-2-bromobenzamides proceeds in a highly enantioselective manner to give N–C axially chiral N-aryl-phenanthridinone derivatives.

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JO - Chem

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ER -

A unique method for highly enantioselective synthesis of N–C axially chiral compounds

Abstract

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