An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Atsushi Nakajima; Toshiki Tajima

doi:10.1016/j.elecom.2009.04.002

An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Atsushi Nakajima, Toshiki Tajima

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

Original language	English
Pages (from-to)	1199-1202
Number of pages	4
Journal	Electrochemistry Communications
Volume	11
Issue number	6
DOIs	https://doi.org/10.1016/j.elecom.2009.04.002
Publication status	Published - 2009 Jun
Externally published	Yes

Keywords

Anion exchange reaction
Anion exchange resin
Electroreduction
Potassium chloride
Supporting electrolyte

ASJC Scopus subject areas

Electrochemistry

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10.1016/j.elecom.2009.04.002

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title = "An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin",

abstract = "We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.",

keywords = "Anion exchange reaction, Anion exchange resin, Electroreduction, Potassium chloride, Supporting electrolyte",

author = "Atsushi Nakajima and Toshiki Tajima",

note = "Funding Information: This work was supported by MEXT{\textquoteright}s program “Promotion of Environmental Improvement for Independence of Young Researchers” under the Special Coordination Funds for Promoting Science and Technology. A.N. thanks a Grant-in-Aid for JSPS Fellows.",

year = "2009",

month = jun,

doi = "10.1016/j.elecom.2009.04.002",

language = "English",

volume = "11",

pages = "1199--1202",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

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TY - JOUR

T1 - An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

AU - Nakajima, Atsushi

AU - Tajima, Toshiki

N1 - Funding Information: This work was supported by MEXT’s program “Promotion of Environmental Improvement for Independence of Young Researchers” under the Special Coordination Funds for Promoting Science and Technology. A.N. thanks a Grant-in-Aid for JSPS Fellows.

PY - 2009/6

Y1 - 2009/6

N2 - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

AB - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

KW - Anion exchange reaction

KW - Anion exchange resin

KW - Electroreduction

KW - Potassium chloride

KW - Supporting electrolyte

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U2 - 10.1016/j.elecom.2009.04.002

DO - 10.1016/j.elecom.2009.04.002

M3 - Article

AN - SCOPUS:67349177734

SN - 1388-2481

VL - 11

SP - 1199

EP - 1202

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 6

ER -

An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Abstract

Keywords

ASJC Scopus subject areas

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