Annealing treatment for enhancing of H2/C3H8separation performance on polysulfone membrane

Irmariza S. Caralin; Alvin R. Widyanto; Nurul Widiastuti; Rika Wijiyanti; Triyanda Gunawan; Zulhairun A. Karim; Mikihiro Nomura; Yuki Yoshida

doi:10.1063/5.0052177

Annealing treatment for enhancing of H₂/C₃H₈separation performance on polysulfone membrane

Irmariza S. Caralin, Alvin R. Widyanto, Nurul Widiastuti, Rika Wijiyanti, Triyanda Gunawan, Zulhairun A. Karim, Mikihiro Nomura, Yuki Yoshida

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

3 Citations (Scopus)

Abstract

Recovery of heavier hydrocarbon gas (i.e. C3H8) from permanent gas (i.e. H2) during gas streams process is a great importance economically. Separation of H2/C3H8 gas using polysulfone (PSF) polymeric membrane was studied with the effect of post-treatment process such as annealing to improve the gas separation performance. PSF membrane annealed using a muffle furnace under vacuum conditions at 150°C for an hour. The result showed that annealing process caused a reduction in the mobility of the polymer chain, which was indicated by a shift of 2θ in XRD results. The cross-section morphology of membrane annealed at 150°C was examined by SEM. Annealing process of PSF membrane enhanced the H2/C3H8 selectivity by 619.77%, from 3.08 to 22.19. It was concluded that post-treatment PSF membrane could improve the H2/C3H8 separation performance compared to PSF membrane without annealing treatment.

Original language	English
Title of host publication	4th International Seminar on Chemistry
Editors	Yuly Kusumawati, Adi Setyo Purnomo
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735441002
DOIs	https://doi.org/10.1063/5.0052177
Publication status	Published - 2021 Jun 24
Event	4th International Seminar on Chemistry, ISoC 2021 - Surabaya, Indonesia Duration: 2020 Oct 7 → 2020 Oct 8

Publication series

Name	AIP Conference Proceedings
Volume	2349
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	4th International Seminar on Chemistry, ISoC 2021
Country/Territory	Indonesia
City	Surabaya
Period	20/10/7 → 20/10/8

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1063/5.0052177

Cite this

Caralin, I. S., Widyanto, A. R., Widiastuti, N., Wijiyanti, R., Gunawan, T., Karim, Z. A., Nomura, M., & Yoshida, Y. (2021). Annealing treatment for enhancing of H₂/C₃H₈separation performance on polysulfone membrane. In Y. Kusumawati, & A. S. Purnomo (Eds.), 4th International Seminar on Chemistry [020065] (AIP Conference Proceedings; Vol. 2349). American Institute of Physics Inc.. https://doi.org/10.1063/5.0052177

Annealing treatment for enhancing of H₂/C₃H₈separation performance on polysulfone membrane. / Caralin, Irmariza S.; Widyanto, Alvin R.; Widiastuti, Nurul et al.
4th International Seminar on Chemistry. ed. / Yuly Kusumawati; Adi Setyo Purnomo. American Institute of Physics Inc., 2021. 020065 (AIP Conference Proceedings; Vol. 2349).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Caralin, IS, Widyanto, AR, Widiastuti, N, Wijiyanti, R, Gunawan, T, Karim, ZA, Nomura, M & Yoshida, Y 2021, Annealing treatment for enhancing of H₂/C₃H₈separation performance on polysulfone membrane. in Y Kusumawati & AS Purnomo (eds), 4th International Seminar on Chemistry., 020065, AIP Conference Proceedings, vol. 2349, American Institute of Physics Inc., 4th International Seminar on Chemistry, ISoC 2021, Surabaya, Indonesia, 20/10/7. https://doi.org/10.1063/5.0052177

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abstract = "Recovery of heavier hydrocarbon gas (i.e. C3H8) from permanent gas (i.e. H2) during gas streams process is a great importance economically. Separation of H2/C3H8 gas using polysulfone (PSF) polymeric membrane was studied with the effect of post-treatment process such as annealing to improve the gas separation performance. PSF membrane annealed using a muffle furnace under vacuum conditions at 150°C for an hour. The result showed that annealing process caused a reduction in the mobility of the polymer chain, which was indicated by a shift of 2θ in XRD results. The cross-section morphology of membrane annealed at 150°C was examined by SEM. Annealing process of PSF membrane enhanced the H2/C3H8 selectivity by 619.77%, from 3.08 to 22.19. It was concluded that post-treatment PSF membrane could improve the H2/C3H8 separation performance compared to PSF membrane without annealing treatment.",

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note = "Funding Information: The authors would like to thank the Ministry of Research and Higher Education of Indonesia for providing the research funding under PMDSU contract no: 135/SP2H/LT/DPRM/IV/2017. The authors also would like to appreciate Pertamina and Pembangunan Perumahan Company for providing the funding, and Shibaura Institute of Technology for supporting Irmariza Shafitri Caralin with student exchange scholarship. Publisher Copyright: {\textcopyright} 2021 Author(s).; 4th International Seminar on Chemistry, ISoC 2021 ; Conference date: 07-10-2020 Through 08-10-2020",

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AU - Caralin, Irmariza S.

AU - Widyanto, Alvin R.

AU - Widiastuti, Nurul

AU - Wijiyanti, Rika

AU - Gunawan, Triyanda

AU - Karim, Zulhairun A.

AU - Nomura, Mikihiro

AU - Yoshida, Yuki

N1 - Funding Information: The authors would like to thank the Ministry of Research and Higher Education of Indonesia for providing the research funding under PMDSU contract no: 135/SP2H/LT/DPRM/IV/2017. The authors also would like to appreciate Pertamina and Pembangunan Perumahan Company for providing the funding, and Shibaura Institute of Technology for supporting Irmariza Shafitri Caralin with student exchange scholarship. Publisher Copyright: © 2021 Author(s).

PY - 2021/6/24

Y1 - 2021/6/24

N2 - Recovery of heavier hydrocarbon gas (i.e. C3H8) from permanent gas (i.e. H2) during gas streams process is a great importance economically. Separation of H2/C3H8 gas using polysulfone (PSF) polymeric membrane was studied with the effect of post-treatment process such as annealing to improve the gas separation performance. PSF membrane annealed using a muffle furnace under vacuum conditions at 150°C for an hour. The result showed that annealing process caused a reduction in the mobility of the polymer chain, which was indicated by a shift of 2θ in XRD results. The cross-section morphology of membrane annealed at 150°C was examined by SEM. Annealing process of PSF membrane enhanced the H2/C3H8 selectivity by 619.77%, from 3.08 to 22.19. It was concluded that post-treatment PSF membrane could improve the H2/C3H8 separation performance compared to PSF membrane without annealing treatment.

AB - Recovery of heavier hydrocarbon gas (i.e. C3H8) from permanent gas (i.e. H2) during gas streams process is a great importance economically. Separation of H2/C3H8 gas using polysulfone (PSF) polymeric membrane was studied with the effect of post-treatment process such as annealing to improve the gas separation performance. PSF membrane annealed using a muffle furnace under vacuum conditions at 150°C for an hour. The result showed that annealing process caused a reduction in the mobility of the polymer chain, which was indicated by a shift of 2θ in XRD results. The cross-section morphology of membrane annealed at 150°C was examined by SEM. Annealing process of PSF membrane enhanced the H2/C3H8 selectivity by 619.77%, from 3.08 to 22.19. It was concluded that post-treatment PSF membrane could improve the H2/C3H8 separation performance compared to PSF membrane without annealing treatment.

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