Coordination assemblies from a Pd(II)-cornered square complex

Makoto Fujita; Masahide Tominaga; Akiko Hori; Bruno Therrien

doi:10.1021/ar040153h

Coordination assemblies from a Pd(II)-cornered square complex

Makoto Fujita, Masahide Tominaga, Akiko Hori, Bruno Therrien

Research output: Contribution to journal › Article › peer-review

1433 Citations (Scopus)

Abstract

The [enPd(II)]²⁺ (en = ethylenediamine) unit has emerged as a versatile building block in molecular self-assembly. In particular, the 90° coordination angle of the metal has been judiciously used in the design of new discrete two- and three-dimensional structures. Our last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd₄ square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.

Original language	English
Pages (from-to)	369-378
Number of pages	10
Journal	Accounts of Chemical Research
Volume	38
Issue number	4
DOIs	https://doi.org/10.1021/ar040153h
Publication status	Published - 2005 Apr 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1021/ar040153h

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AU - Tominaga, Masahide

AU - Hori, Akiko

AU - Therrien, Bruno

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AB - The [enPd(II)]2+ (en = ethylenediamine) unit has emerged as a versatile building block in molecular self-assembly. In particular, the 90° coordination angle of the metal has been judiciously used in the design of new discrete two- and three-dimensional structures. Our last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd4 square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.

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Coordination assemblies from a Pd(II)-cornered square complex

Abstract

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