Abstract
We have successfully developed a novel electrolytic system using solid-supported bases for in situ generation of a supporting electrolyte from methanol as a solvent. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide using solid-supported bases was carried out to provide the α-methoxylated product in good to excellent yields. The α-methoxylated product and solid-supported bases were easily separated by only filtration, and the separated solid-supported bases were recyclable. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide was successfully carried out 10 times by the recycling of silica gel-supported piperidine in good yields.
| Original language | English |
|---|---|
| Pages (from-to) | 2848-2849 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 127 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2005 Mar 9 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry