TY - JOUR
T1 - Development of hydrogen permselective membranes for propylene production
AU - Ishii, Katsunori
AU - Nagataki, Yuhei
AU - Yoshiura, Junko
AU - Saito, Yuta
AU - Nagataki, Takaya
AU - Nomura, Mikihiro
PY - 2021/5/20
Y1 - 2021/5/20
N2 - Silica hybrid membranes were developed for a membrane reactor for propane dehydrogenation reaction using a counter diffusion chemical vapor deposition (CVD) method. The effects of the alkyl chains in the silica precursor were investigated to control the membrane properties. Additionally, a membrane reactor test using a CVD silica membrane for the membrane reactor was performed and compared with only using a catalytic bed reactor. An ethyltrimethoxysilane-derived membrane deposited at 500°C exhibited a high H2/C3H8 selectivity of 650. The C3H8 conversion was 53% with C3H6 selectivity of 69% for the 600°C reaction in the membrane reactor. The conversion was slightly higher than that at equilibrium.
AB - Silica hybrid membranes were developed for a membrane reactor for propane dehydrogenation reaction using a counter diffusion chemical vapor deposition (CVD) method. The effects of the alkyl chains in the silica precursor were investigated to control the membrane properties. Additionally, a membrane reactor test using a CVD silica membrane for the membrane reactor was performed and compared with only using a catalytic bed reactor. An ethyltrimethoxysilane-derived membrane deposited at 500°C exhibited a high H2/C3H8 selectivity of 650. The C3H8 conversion was 53% with C3H6 selectivity of 69% for the 600°C reaction in the membrane reactor. The conversion was slightly higher than that at equilibrium.
KW - Counter diffusion CVD method
KW - Propane dehydrogenation
KW - Silica hybrid membrane
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U2 - 10.1252/jcej.20we082
DO - 10.1252/jcej.20we082
M3 - Article
AN - SCOPUS:85107015053
SN - 0021-9592
VL - 54
SP - 260
EP - 265
JO - Journal of Chemical Engineering of Japan
JF - Journal of Chemical Engineering of Japan
IS - 5
ER -