Double naphthalene-tagged cyclodextrin-peptide capable of exhibiting guest-induced naphthalene excimer fluorescence

Dewi Yana; Tomoko Shimizu; Keita Hamasaki; Hisakazu Mihara; Akihiko Ueno

doi:10.1002/1521-3927(20020101)23:1<11::AID-MARC11>3.0.CO;2-D

Double naphthalene-tagged cyclodextrin-peptide capable of exhibiting guest-induced naphthalene excimer fluorescence

Dewi Yana, Tomoko Shimizu, Keita Hamasaki, Hisakazu Mihara, Akihiko Ueno

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A cyclodextrin-peptide hybrid (17NNβ) bearing two napthalene units in the peptide side chain has been designed and synthesized as a novel chemosensor molecule. Circular dichroism study of the compound revealed that the peptide has helix structure with a helix content of 41%. The peptide revealed both monomer and exciter emission and the intensity of the exciter amusesen increased while that of the monomer emission decreased upon addition of the guest compound. This behavior was observed for various guest molecules, sigh-getting that the system can be used for detecting molecellose in aqueous solution.

Original language	English
Pages (from-to)	11-15
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	23
Issue number	1
DOIs	https://doi.org/10.1002/1521-3927(20020101)23:1<11::AID-MARC11>3.0.CO;2-D
Publication status	Published - 2002 Jan 9
Externally published	Yes

Keywords

Cyclodextrins
Excimer fluorescence
Host-guest systems
Peptide

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/1521-3927(20020101)23:1<11::AID-MARC11>3.0.CO;2-D

Cite this

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abstract = "A cyclodextrin-peptide hybrid (17NNβ) bearing two napthalene units in the peptide side chain has been designed and synthesized as a novel chemosensor molecule. Circular dichroism study of the compound revealed that the peptide has helix structure with a helix content of 41%. The peptide revealed both monomer and exciter emission and the intensity of the exciter amusesen increased while that of the monomer emission decreased upon addition of the guest compound. This behavior was observed for various guest molecules, sigh-getting that the system can be used for detecting molecellose in aqueous solution.",

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T1 - Double naphthalene-tagged cyclodextrin-peptide capable of exhibiting guest-induced naphthalene excimer fluorescence

AU - Yana, Dewi

AU - Shimizu, Tomoko

AU - Hamasaki, Keita

AU - Mihara, Hisakazu

AU - Ueno, Akihiko

PY - 2002/1/9

Y1 - 2002/1/9

N2 - A cyclodextrin-peptide hybrid (17NNβ) bearing two napthalene units in the peptide side chain has been designed and synthesized as a novel chemosensor molecule. Circular dichroism study of the compound revealed that the peptide has helix structure with a helix content of 41%. The peptide revealed both monomer and exciter emission and the intensity of the exciter amusesen increased while that of the monomer emission decreased upon addition of the guest compound. This behavior was observed for various guest molecules, sigh-getting that the system can be used for detecting molecellose in aqueous solution.

AB - A cyclodextrin-peptide hybrid (17NNβ) bearing two napthalene units in the peptide side chain has been designed and synthesized as a novel chemosensor molecule. Circular dichroism study of the compound revealed that the peptide has helix structure with a helix content of 41%. The peptide revealed both monomer and exciter emission and the intensity of the exciter amusesen increased while that of the monomer emission decreased upon addition of the guest compound. This behavior was observed for various guest molecules, sigh-getting that the system can be used for detecting molecellose in aqueous solution.

KW - Cyclodextrins

KW - Excimer fluorescence

KW - Host-guest systems

KW - Peptide

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Double naphthalene-tagged cyclodextrin-peptide capable of exhibiting guest-induced naphthalene excimer fluorescence

Abstract

Keywords

ASJC Scopus subject areas

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