Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Yi Shen; Toshiki Tajima; Mahito Atobe; Toshio Fuchigami

doi:10.5796/electrochemistry.72.849

Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Yi Shen, Toshiki Tajima, Mahito Atobe, Toshio Fuchigami

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

Original language	English
Pages (from-to)	849-851
Number of pages	3
Journal	Electrochemistry
Volume	72
Issue number	12
DOIs	https://doi.org/10.5796/electrochemistry.72.849
Publication status	Published - 2004 Dec
Externally published	Yes

Keywords

Controlled Potential Electrolysis
Ionic Liquid
Mediator

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.72.849

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AU - Shen, Yi

AU - Tajima, Toshiki

AU - Atobe, Mahito

AU - Fuchigami, Toshio

PY - 2004/12

Y1 - 2004/12

N2 - The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

AB - The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

KW - Controlled Potential Electrolysis

KW - Ionic Liquid

KW - Mediator

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JF - Electrochemistry

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ER -

Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Abstract

Keywords

ASJC Scopus subject areas

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