Estimation of bonding nature using diamagnetic susceptibility

Keisuke Tomiyasu; Toyoto Sato; Shin Ichi Orimo

doi:10.1039/c5cc02351c

Estimation of bonding nature using diamagnetic susceptibility

Keisuke Tomiyasu, Toyoto Sato, Shin Ichi Orimo

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.

Original language	English
Pages (from-to)	8691-8694
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	41
DOIs	https://doi.org/10.1039/c5cc02351c
Publication status	Published - 2015 May 21
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc02351c

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title = "Estimation of bonding nature using diamagnetic susceptibility",

abstract = "A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.",

author = "Keisuke Tomiyasu and Toyoto Sato and Orimo, {Shin Ichi}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c5cc02351c",

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AU - Tomiyasu, Keisuke

AU - Sato, Toyoto

AU - Orimo, Shin Ichi

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/5/21

Y1 - 2015/5/21

N2 - A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.

AB - A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.

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DO - 10.1039/c5cc02351c

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JO - Chemical Communications

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Estimation of bonding nature using diamagnetic susceptibility

Abstract

ASJC Scopus subject areas

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