Formation of superabundant vacancies in Pd-H alloys

Yuh Fukai, Yasuyuki Ishii, Yoshihiro Goto, Kuniaki Watanabe

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39 Citations (Scopus)


Temporal variation of the lattice parameter of Pd was measured under high hydrogen pressures (2-5 GPa) and temperatures (672-896 °C) by X-ray diffraction using a synchrotron radiation, and observed lattice contraction was interpreted as being due to the formation of a large number of vacancy-hydrogen (Vac-H) clusters, i.e. superabundant vacancies. Analysis of the result led to the conclusion that a major part of Vac-H clusters (amounting to approximately 10 at.%) were introduced by diffusion from the surface, after a small number of them had been formed at some internal sources. The thermal-equilibrium concentration of Vac-H clusters at high temperatures shows a saturation behavior, which indicates the presence of a maximum possible concentration (ca. 16 at.%) of the clusters. The formation energy, entropy and volume of a Vac-H cluster are found to be 0.72 eV, 7.2 k and 0.60 Ω, respectively, and the migration energy and volume are 1.20 eV and 0.49 Ω, respectively. Various other implications of the results are also discussed.

Original languageEnglish
Pages (from-to)121-132
Number of pages12
JournalJournal of Alloys and Compounds
Issue number1-2
Publication statusPublished - 2000 Dec 15
Externally publishedYes

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry


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