Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C60-porphyrin light-to-photocurrent conversion system

Atsushi Ikeda; Tsukasa Hatano; Toshifumi Konishi; Jun Ichi Kikuchi; Seiji Shinkai

doi:10.1016/S0040-4020(03)00417-4

Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C₆₀-porphyrin light-to-photocurrent conversion system

Atsushi Ikeda, Tsukasa Hatano, Toshifumi Konishi, Jun Ichi Kikuchi, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

In a light-to-photocurrent conversion system based on a C₆₀-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units.

Original language	English
Pages (from-to)	3537-3540
Number of pages	4
Journal	Tetrahedron
Volume	59
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4020(03)00417-4
Publication status	Published - 2003 May 5
Externally published	Yes

Keywords

Calixarenes
Cyclodextrins
Fullerenes
Photocurrent
Porphyrins

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4020(03)00417-4

Cite this

@article{696446a91ec9461fa9d1b5306803ec66,

title = "Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C60-porphyrin light-to-photocurrent conversion system",

abstract = "In a light-to-photocurrent conversion system based on a C60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units.",

keywords = "Calixarenes, Cyclodextrins, Fullerenes, Photocurrent, Porphyrins",

author = "Atsushi Ikeda and Tsukasa Hatano and Toshifumi Konishi and Kikuchi, {Jun Ichi} and Seiji Shinkai",

note = "Funding Information: We thank Mr H. Horiuchi for his skill in preparing specially designed glass cells. This work was supported by PRESTO in Japan Science and Technology Corporation (JST) and also by the Grants-in-Aid for Scientific Research (No. 11750749) from the Ministry of Education, Science and Culture of Japan.",

year = "2003",

month = may,

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doi = "10.1016/S0040-4020(03)00417-4",

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journal = "Tetrahedron",

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T1 - Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C60-porphyrin light-to-photocurrent conversion system

AU - Ikeda, Atsushi

AU - Hatano, Tsukasa

AU - Konishi, Toshifumi

AU - Kikuchi, Jun Ichi

AU - Shinkai, Seiji

N1 - Funding Information: We thank Mr H. Horiuchi for his skill in preparing specially designed glass cells. This work was supported by PRESTO in Japan Science and Technology Corporation (JST) and also by the Grants-in-Aid for Scientific Research (No. 11750749) from the Ministry of Education, Science and Culture of Japan.

PY - 2003/5/5

Y1 - 2003/5/5

N2 - In a light-to-photocurrent conversion system based on a C60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units.

AB - In a light-to-photocurrent conversion system based on a C60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units.

KW - Calixarenes

KW - Cyclodextrins

KW - Fullerenes

KW - Photocurrent

KW - Porphyrins

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