@inproceedings{decc0dafa83d448ca5ef1c727ebbc1d0,
title = "Minimizing the influence of experimental uncertainty for delivered methane/steam reforming kinetic equation by the optimized design of experimentation",
abstract = "This paper presents study on methane/steam reforming process and method to develop effective experimental-calculation procedure to deliver the reliable kinetic reaction rate expression with the decreased number of necessary experimental measurements for the calculations of the empirical parameters. The experimental studies were conducted on the NiO/YSZ (60/40vol%) catalyst, one of the most typical materials, for Solid Oxide Fuel Cell anodes. By the analysis with the Orthogonal Least Squares method and an analysis of a-posteriori covariance matrix, the experimentation process has been optimized. The proposed systematic approach was applied to evaluate the minimal number of measurements required to achieve the assumed accuracy of final solution and to reveal the influence of distribution of experimental condition for the quality of final reaction kinetic equation. It was proved that the number of experimental measurements can be reduced without significant deterioration in the quality of solution, if the dismissed measurements are properly chosen.",
author = "A. Sciazko and Y. Komatsu and G. Brus and N. Shikazono and S. Kimijima and Szmyd, {J. S.}",
note = "Funding Information: This work was partially supported by the Polish National Science Centre (grant no. 2015/17/N/ST8/01185) and by the Japan Society for the Promotion of Science (JSPS) Program of the Postdoctoral Fellowship Research in Japan. Publisher Copyright: {\textcopyright} The Electrochemical Society.; 15th International Symposium on Solid Oxide Fuel Cells, SOFC 2017 ; Conference date: 23-07-2017 Through 28-07-2017",
year = "2017",
month = may,
day = "30",
doi = "10.1149/07801.2633ecst",
language = "English",
series = "ECS Transactions",
publisher = "Electrochemical Society Inc.",
number = "1",
pages = "2633--2643",
editor = "Singhal, {S. C.} and T. Kawada",
booktitle = "ECS Transactions",
edition = "1",
}