Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light

Yuting Wang; Koji Yazawa; Qingyu Wang; Takunori Harada; Shuhei Shimoda; Zhiyi Song; Masayoshi Bando; Naofumi Naga; Tamaki Nakano

doi:10.1039/d1cc02671b

Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light

Yuting Wang, Koji Yazawa, Qingyu Wang, Takunori Harada, Shuhei Shimoda, Zhiyi Song, Masayoshi Bando, Naofumi Naga, Tamaki Nakano

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Axial chirality was induced by circularly polarized light to covalent organic frameworks as well as hyperbranched polymers composed of bezene-1,3,5-triyl core units and oligo(benzene-1,4-diyl) as linker units where variation in induction efficiency was rationally interpreted in terms of internal rotation dynamics studied through CPMAS¹³C NMR experiments including CODEX measurements.

Original language	English
Pages (from-to)	7681-7684
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	62
DOIs	https://doi.org/10.1039/d1cc02671b
Publication status	Published - 2021 Aug 11

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light",

abstract = "Axial chirality was induced by circularly polarized light to covalent organic frameworks as well as hyperbranched polymers composed of bezene-1,3,5-triyl core units and oligo(benzene-1,4-diyl) as linker units where variation in induction efficiency was rationally interpreted in terms of internal rotation dynamics studied through CPMAS13C NMR experiments including CODEX measurements.",

author = "Yuting Wang and Koji Yazawa and Qingyu Wang and Takunori Harada and Shuhei Shimoda and Zhiyi Song and Masayoshi Bando and Naofumi Naga and Tamaki Nakano",

note = "Funding Information: This work was supported in part by the MEXT/JSPS KAKENHI Grant Number JP 19H02759 and in part by the JST grant No. JPMJTMl9E4. The Technical Division of Institute for Catalysis, Hokkaido University is acknowledged for technical support. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

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month = aug,

day = "11",

doi = "10.1039/d1cc02671b",

language = "English",

volume = "57",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light

AU - Wang, Yuting

AU - Yazawa, Koji

AU - Wang, Qingyu

AU - Harada, Takunori

AU - Shimoda, Shuhei

AU - Song, Zhiyi

AU - Bando, Masayoshi

AU - Naga, Naofumi

AU - Nakano, Tamaki

N1 - Funding Information: This work was supported in part by the MEXT/JSPS KAKENHI Grant Number JP 19H02759 and in part by the JST grant No. JPMJTMl9E4. The Technical Division of Institute for Catalysis, Hokkaido University is acknowledged for technical support. Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/8/11

Y1 - 2021/8/11

N2 - Axial chirality was induced by circularly polarized light to covalent organic frameworks as well as hyperbranched polymers composed of bezene-1,3,5-triyl core units and oligo(benzene-1,4-diyl) as linker units where variation in induction efficiency was rationally interpreted in terms of internal rotation dynamics studied through CPMAS13C NMR experiments including CODEX measurements.

AB - Axial chirality was induced by circularly polarized light to covalent organic frameworks as well as hyperbranched polymers composed of bezene-1,3,5-triyl core units and oligo(benzene-1,4-diyl) as linker units where variation in induction efficiency was rationally interpreted in terms of internal rotation dynamics studied through CPMAS13C NMR experiments including CODEX measurements.

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JO - Chemical Communications

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ER -

Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light

Abstract

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