Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds

Masayuki Kirihara; Takuya Noguchi; Hiroko Kakuda; Tatsuhiro Akimoto; Akihiro Shimajiri; Minori Morishita; Akihiko Hatano; Yoshiro Hirai

doi:10.1016/j.tetlet.2006.03.120

Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds

Masayuki Kirihara, Takuya Noguchi, Hiroko Kakuda, Tatsuhiro Akimoto, Akihiro Shimajiri, Minori Morishita, Akihiko Hatano, Yoshiro Hirai

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride in electron-rich aromatic compounds causes the Friedel-Crafts alkylation to produce allylated or cyclopropylated aromatic compounds.

Original language	English
Pages (from-to)	3777-3780
Number of pages	4
Journal	Tetrahedron Letters
Volume	47
Issue number	22
DOIs	https://doi.org/10.1016/j.tetlet.2006.03.120
Publication status	Published - 2006 May 29
Externally published	Yes

Keywords

Cyclopropyl silyl ether
Diethylaminosulfur trifluoride
Friedel-Crafts allylation
Friedel-Crafts cyclopropylation

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2006.03.120

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Kirihara, M., Noguchi, T., Kakuda, H., Akimoto, T., Shimajiri, A., Morishita, M., Hatano, A., & Hirai, Y. (2006). Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds. Tetrahedron Letters, 47(22), 3777-3780. https://doi.org/10.1016/j.tetlet.2006.03.120

Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2 : The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds. / Kirihara, Masayuki; Noguchi, Takuya; Kakuda, Hiroko et al.

In: Tetrahedron Letters, Vol. 47, No. 22, 29.05.2006, p. 3777-3780.

Research output: Contribution to journal › Article › peer-review

Kirihara, M, Noguchi, T, Kakuda, H, Akimoto, T, Shimajiri, A, Morishita, M, Hatano, A & Hirai, Y 2006, 'Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds', Tetrahedron Letters, vol. 47, no. 22, pp. 3777-3780. https://doi.org/10.1016/j.tetlet.2006.03.120

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abstract = "The reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride in electron-rich aromatic compounds causes the Friedel-Crafts alkylation to produce allylated or cyclopropylated aromatic compounds.",

keywords = "Cyclopropyl silyl ether, Diethylaminosulfur trifluoride, Friedel-Crafts allylation, Friedel-Crafts cyclopropylation",

author = "Masayuki Kirihara and Takuya Noguchi and Hiroko Kakuda and Tatsuhiro Akimoto and Akihiro Shimajiri and Minori Morishita and Akihiko Hatano and Yoshiro Hirai",

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T2 - The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds

AU - Kirihara, Masayuki

AU - Noguchi, Takuya

AU - Kakuda, Hiroko

AU - Akimoto, Tatsuhiro

AU - Shimajiri, Akihiro

AU - Morishita, Minori

AU - Hatano, Akihiko

AU - Hirai, Yoshiro

PY - 2006/5/29

Y1 - 2006/5/29

N2 - The reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride in electron-rich aromatic compounds causes the Friedel-Crafts alkylation to produce allylated or cyclopropylated aromatic compounds.

AB - The reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride in electron-rich aromatic compounds causes the Friedel-Crafts alkylation to produce allylated or cyclopropylated aromatic compounds.

KW - Cyclopropyl silyl ether

KW - Diethylaminosulfur trifluoride

KW - Friedel-Crafts allylation

KW - Friedel-Crafts cyclopropylation

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Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds

Abstract

Keywords

ASJC Scopus subject areas

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