Treatment of 1-diethylphosphonyl- or 1-phenyl-sulfonyl-2-(iodomethyl)cyclopropane-l-carboxylate with Et3B leads to an unsymmetrical allylated active methine radical species that gives functionalized cyclopentane derivatives with high stereoselectivity through iodine atom transfer [3 + 2] cycloaddition reaction with alkenes.
|Number of pages||4|
|Journal||Journal of Organic Chemistry|
|Publication status||Published - 2004 Apr 2|
ASJC Scopus subject areas
- Organic Chemistry