Study on molecular behavior in oxidation of insulating oil using terahertz spectroscopy

Nobuaki Nishimura; Ryuichi Ogura; Satoshi Matsumoto; Maya Mizuno; Kaori Fukunaga

doi:10.1541/ieejfms.131.943

Study on molecular behavior in oxidation of insulating oil using terahertz spectroscopy

Nobuaki Nishimura, Ryuichi Ogura, Satoshi Matsumoto, Maya Mizuno, Kaori Fukunaga

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The number of aged power equipment increases and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes the basic study on molecular behavior in oxidation process of insulating oil by terahertz spectroscopy. The oxidation process of insulating oil was modeled by using various compositions of dodecane and 2-octanol. From the terahertz measurements, the absorption related to hydroxyl groups (-OH) was significantly observed between 6 and 7 THz. The absorption band was also observed in accelerated aging alkylbenzene used in power equipments as insulating oil, and sensitive to hydrogen bonds.

Original language	English
Pages (from-to)	943-948
Number of pages	6
Journal	IEEJ Transactions on Fundamentals and Materials
Volume	131
Issue number	11
DOIs	https://doi.org/10.1541/ieejfms.131.943
Publication status	Published - 2011 Dec 5

Keywords

Absorption characteristics
Hydrogen bond
Insulating oil
Molecular behavior
Oxidation
Terahertz

ASJC Scopus subject areas

Electrical and Electronic Engineering

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10.1541/ieejfms.131.943

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title = "Study on molecular behavior in oxidation of insulating oil using terahertz spectroscopy",

abstract = "The number of aged power equipment increases and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes the basic study on molecular behavior in oxidation process of insulating oil by terahertz spectroscopy. The oxidation process of insulating oil was modeled by using various compositions of dodecane and 2-octanol. From the terahertz measurements, the absorption related to hydroxyl groups (-OH) was significantly observed between 6 and 7 THz. The absorption band was also observed in accelerated aging alkylbenzene used in power equipments as insulating oil, and sensitive to hydrogen bonds.",

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AU - Nishimura, Nobuaki

AU - Ogura, Ryuichi

AU - Matsumoto, Satoshi

AU - Mizuno, Maya

AU - Fukunaga, Kaori

PY - 2011/12/5

Y1 - 2011/12/5

N2 - The number of aged power equipment increases and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes the basic study on molecular behavior in oxidation process of insulating oil by terahertz spectroscopy. The oxidation process of insulating oil was modeled by using various compositions of dodecane and 2-octanol. From the terahertz measurements, the absorption related to hydroxyl groups (-OH) was significantly observed between 6 and 7 THz. The absorption band was also observed in accelerated aging alkylbenzene used in power equipments as insulating oil, and sensitive to hydrogen bonds.

AB - The number of aged power equipment increases and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes the basic study on molecular behavior in oxidation process of insulating oil by terahertz spectroscopy. The oxidation process of insulating oil was modeled by using various compositions of dodecane and 2-octanol. From the terahertz measurements, the absorption related to hydroxyl groups (-OH) was significantly observed between 6 and 7 THz. The absorption band was also observed in accelerated aging alkylbenzene used in power equipments as insulating oil, and sensitive to hydrogen bonds.

KW - Absorption characteristics

KW - Hydrogen bond

KW - Insulating oil

KW - Molecular behavior

KW - Oxidation

KW - Terahertz

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Study on molecular behavior in oxidation of insulating oil using terahertz spectroscopy

Abstract

Keywords

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