TY - JOUR
T1 - Synthesis and characterisation of RuSr2NdxGd 1-xCu2O8 compounds (x = 0, 0.03, 0.06 and 0.12)
AU - Mele, P.
AU - Artini, C.
AU - Masini, R.
AU - Costa, G. A.
AU - Hu, A.
AU - Chikumoto, N.
AU - Murakami, M.
N1 - Funding Information:
P.M. acknowledges the Japanese Society for the Promotion of Science (JSPS) for fellowship No. P03852.
Funding Information:
This work was partially supported by the New Energy and industrial Technology Development Organisation (NEDO), Japan, as Collaborative Research and Development of Fundamental Technologies for Superconductivity Applications.
PY - 2004/10
Y1 - 2004/10
N2 - RuSr2NdxGd1-xCu2O8 samples (x=0, 0.03, 0.06 and 0.12) were synthesised by a solid state route, using mixed rare earth oxides (NdxGd1-x)2O 3, prepared by a co-precipitation method, as precursors. Magnetoresistance measurements showed that the resistive transition temperature decreased and broadened with increasing Nd doping, suggesting that Nd really entered the lattice. The resistive transition curves in applied field exhibited typical polycrystalline behaviour with two peaks in their first derivative, identified as intra and intergrain superconducting transitions. XRD data also supported the fact that Nd ion entered the Ru-1212 lattice, yielding an ordered tetragonal structure at low Nd doping level. At higher Nd concentrations, the structure becomes disordered probably due to Nd/Sr solid solution.
AB - RuSr2NdxGd1-xCu2O8 samples (x=0, 0.03, 0.06 and 0.12) were synthesised by a solid state route, using mixed rare earth oxides (NdxGd1-x)2O 3, prepared by a co-precipitation method, as precursors. Magnetoresistance measurements showed that the resistive transition temperature decreased and broadened with increasing Nd doping, suggesting that Nd really entered the lattice. The resistive transition curves in applied field exhibited typical polycrystalline behaviour with two peaks in their first derivative, identified as intra and intergrain superconducting transitions. XRD data also supported the fact that Nd ion entered the Ru-1212 lattice, yielding an ordered tetragonal structure at low Nd doping level. At higher Nd concentrations, the structure becomes disordered probably due to Nd/Sr solid solution.
KW - Ruthenocuprates
KW - Substitutions
KW - Superconductivity
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=4644370277&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4644370277&partnerID=8YFLogxK
U2 - 10.1016/j.physc.2004.01.095
DO - 10.1016/j.physc.2004.01.095
M3 - Article
AN - SCOPUS:4644370277
SN - 0921-4534
VL - 412-414
SP - 196
EP - 200
JO - Physica C: Superconductivity and its Applications
JF - Physica C: Superconductivity and its Applications
IS - SPEC. ISS.
ER -