TY - JOUR
T1 - Synthesis and crystal structures of fluorinated β-diketonate metal (Al3+, Co2+, Ni2+, and Cu2+) complexes
AU - Hori, Akiko
AU - Shinohe, Ayaka
AU - Takatani, Shohei
AU - Miyamoto, Takeshi K.
PY - 2009
Y1 - 2009
N2 - Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5-) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].
AB - Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5-) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].
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U2 - 10.1246/bcsj.82.96
DO - 10.1246/bcsj.82.96
M3 - Article
AN - SCOPUS:58349121422
SN - 0009-2673
VL - 82
SP - 96
EP - 98
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 1
ER -