Ultrahigh flux zeolite membranes for hydrogen separation

Mikihiro Nomura; K. Oura; A. Ikeda; T. Saito; H. Tawarayama; S. Ishikawa; K. Kuwahara

Ultrahigh flux zeolite membranes for hydrogen separation

Mikihiro Nomura, K. Oura, A. Ikeda, T. Saito, H. Tawarayama, S. Ishikawa, K. Kuwahara

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

MFI zeolite membranes with high gas permselectivities were successfully prepared on novel porous silica substrates. Procedures for coating of MFI seed crystals were important due to the -potential between the substrates and the seed crystals. Dense MFI membranes were obtained from the seed slurry of pH 2, because the both isoelectric pH of the silica substrates and the MFI seeds are almost the same at 2. N₂ permeance was 3.7 x 10^-6 mol m^-2 s^-1 Pa^-1 with high N₂/SF₆ permeance ratio of 328 through the membrane prepared on the thin silica substrate of 1.3 mm. Molecular size of SF₆ is smaller than that of toluene indicating that this membrane can be applied for the decomposition reaction of organic hydrides such as methyl-cyclohexane to produce hydrogen.

Original language	English
Title of host publication	WHEC 2016 - 21st World Hydrogen Energy Conference 2016, Proceedings
Publisher	Spanish Hydrogen Association - Asociacion Espanola del Hidrogeno, AEH2
Pages	520-522
Number of pages	3
Publication status	Published - 2016
Event	21st World Hydrogen Energy Conference 2016, WHEC 2016 - Zaragoza, Spain Duration: 2016 Jun 13 → 2016 Jun 16

Other

Other	21st World Hydrogen Energy Conference 2016, WHEC 2016
Country/Territory	Spain
City	Zaragoza
Period	16/6/13 → 16/6/16

ASJC Scopus subject areas

Fuel Technology
Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology

Cite this

Nomura, M, Oura, K, Ikeda, A, Saito, T, Tawarayama, H, Ishikawa, S & Kuwahara, K 2016, Ultrahigh flux zeolite membranes for hydrogen separation. in WHEC 2016 - 21st World Hydrogen Energy Conference 2016, Proceedings. Spanish Hydrogen Association - Asociacion Espanola del Hidrogeno, AEH2, pp. 520-522, 21st World Hydrogen Energy Conference 2016, WHEC 2016, Zaragoza, Spain, 16/6/13.

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title = "Ultrahigh flux zeolite membranes for hydrogen separation",

abstract = "MFI zeolite membranes with high gas permselectivities were successfully prepared on novel porous silica substrates. Procedures for coating of MFI seed crystals were important due to the -potential between the substrates and the seed crystals. Dense MFI membranes were obtained from the seed slurry of pH 2, because the both isoelectric pH of the silica substrates and the MFI seeds are almost the same at 2. N2 permeance was 3.7 x 10-6 mol m-2 s-1 Pa-1 with high N2/SF6 permeance ratio of 328 through the membrane prepared on the thin silica substrate of 1.3 mm. Molecular size of SF6 is smaller than that of toluene indicating that this membrane can be applied for the decomposition reaction of organic hydrides such as methyl-cyclohexane to produce hydrogen.",

author = "Mikihiro Nomura and K. Oura and A. Ikeda and T. Saito and H. Tawarayama and S. Ishikawa and K. Kuwahara",

year = "2016",

language = "English",

pages = "520--522",

booktitle = "WHEC 2016 - 21st World Hydrogen Energy Conference 2016, Proceedings",

publisher = "Spanish Hydrogen Association - Asociacion Espanola del Hidrogeno, AEH2",

note = "21st World Hydrogen Energy Conference 2016, WHEC 2016 ; Conference date: 13-06-2016 Through 16-06-2016",

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TY - GEN

T1 - Ultrahigh flux zeolite membranes for hydrogen separation

AU - Nomura, Mikihiro

AU - Oura, K.

AU - Ikeda, A.

AU - Saito, T.

AU - Tawarayama, H.

AU - Ishikawa, S.

AU - Kuwahara, K.

PY - 2016

Y1 - 2016

N2 - MFI zeolite membranes with high gas permselectivities were successfully prepared on novel porous silica substrates. Procedures for coating of MFI seed crystals were important due to the -potential between the substrates and the seed crystals. Dense MFI membranes were obtained from the seed slurry of pH 2, because the both isoelectric pH of the silica substrates and the MFI seeds are almost the same at 2. N2 permeance was 3.7 x 10-6 mol m-2 s-1 Pa-1 with high N2/SF6 permeance ratio of 328 through the membrane prepared on the thin silica substrate of 1.3 mm. Molecular size of SF6 is smaller than that of toluene indicating that this membrane can be applied for the decomposition reaction of organic hydrides such as methyl-cyclohexane to produce hydrogen.

AB - MFI zeolite membranes with high gas permselectivities were successfully prepared on novel porous silica substrates. Procedures for coating of MFI seed crystals were important due to the -potential between the substrates and the seed crystals. Dense MFI membranes were obtained from the seed slurry of pH 2, because the both isoelectric pH of the silica substrates and the MFI seeds are almost the same at 2. N2 permeance was 3.7 x 10-6 mol m-2 s-1 Pa-1 with high N2/SF6 permeance ratio of 328 through the membrane prepared on the thin silica substrate of 1.3 mm. Molecular size of SF6 is smaller than that of toluene indicating that this membrane can be applied for the decomposition reaction of organic hydrides such as methyl-cyclohexane to produce hydrogen.

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M3 - Conference contribution

AN - SCOPUS:85016964155

SP - 520

EP - 522

BT - WHEC 2016 - 21st World Hydrogen Energy Conference 2016, Proceedings

PB - Spanish Hydrogen Association - Asociacion Espanola del Hidrogeno, AEH2

T2 - 21st World Hydrogen Energy Conference 2016, WHEC 2016

Y2 - 13 June 2016 through 16 June 2016

ER -

Ultrahigh flux zeolite membranes for hydrogen separation

Abstract

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ASJC Scopus subject areas

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