Bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars

Takashi Yamanoi; Ryo Inoue; Sho Matsuda; Keita Hamasaki

doi:10.2174/157017808783330289

Bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars

Takashi Yamanoi, Ryo Inoue, Sho Matsuda, Keita Hamasaki

研究成果: Article › 査読

8 被引用数 (Scopus)

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This paper describes the O-glycoside formation from 1-hydroxy sugars by the bismuth(III) triflate-catalyzed dehydrative glycosidation. The reactions of the 1-hydroxy sugars with some primary alcohols in the presence of only 5 mol% bismuth(III) triflate at reflux for 15 min in dichloromethane afforded the O-glycosides in good yields. This paper clarifies several important properties during the bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars.

本文言語	English
ページ（範囲）	30-33
ページ数	4
ジャーナル	Letters in Organic Chemistry
巻	5
号	1
DOI	https://doi.org/10.2174/157017808783330289
出版ステータス	Published - 2008 1月

ASJC Scopus subject areas

生化学
有機化学

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abstract = "This paper describes the O-glycoside formation from 1-hydroxy sugars by the bismuth(III) triflate-catalyzed dehydrative glycosidation. The reactions of the 1-hydroxy sugars with some primary alcohols in the presence of only 5 mol% bismuth(III) triflate at reflux for 15 min in dichloromethane afforded the O-glycosides in good yields. This paper clarifies several important properties during the bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars.",

keywords = "1,1'-disaccharide, 1-hydroxy sugar, Bismuth(III) triflate, Glycosidation, Glycoside",

author = "Takashi Yamanoi and Ryo Inoue and Sho Matsuda and Keita Hamasaki",

year = "2008",

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doi = "10.2174/157017808783330289",

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AB - This paper describes the O-glycoside formation from 1-hydroxy sugars by the bismuth(III) triflate-catalyzed dehydrative glycosidation. The reactions of the 1-hydroxy sugars with some primary alcohols in the presence of only 5 mol% bismuth(III) triflate at reflux for 15 min in dichloromethane afforded the O-glycosides in good yields. This paper clarifies several important properties during the bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars.

KW - 1,1'-disaccharide

KW - 1-hydroxy sugar

KW - Bismuth(III) triflate

KW - Glycosidation

KW - Glycoside

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Bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars

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