@article{7e97d88408734b838d280e62e1f4860f,
title = "Catalytic enantioselective synthesis of atropisomeric indoles with an N-C chiral axis",
abstract = "(Chemical Equation Presented) A pivotal role: In the presence of (R)-(-)-5,5′-bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4, 4′-bi-1,3-benzodioxole-PdCl2 [(R)-SEGPHOS-PdCl2], 5-endo-hydroaminocyclization of achiral ortho-alkynylanilines proceeds in an enantioselective manner to give optically active, axially chiral indoles (see scheme).",
keywords = "Atropisomerism, Enantioselectivity, Indoles, Palladium, Phosphane ligands",
author = "Nobutaka Ototake and Yudai Morimoto and Ayano Mokuya and Haruhiko Fukaya and Yasuo Shida and Osamu Kitagawa",
note = "Copyright: Copyright 2010 Elsevier B.V., All rights reserved.",
year = "2010",
month = jun,
day = "18",
doi = "10.1002/chem.201000243",
language = "English",
volume = "16",
pages = "6752--6755",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "23",
}