抄録
A new molecular design of fullerene derivatives exhibiting trigger-responsive self-aggregation in organic solvents has been established. Calix[4]arene was covalently connected with fullerene in order to apply host-guest interaction to the aggregation control. The self-assembly behaviour was studied in organic solvents by UV-vis absorption spectroscopy, dynamic light scattering and transmission electron microscopy. Results show that the bisfullerene formed self-aggregations with a low polydispersity index due to the fullerenes' tendency to aggregate in polar organic solvents. Furthermore, the aggregate sizes can be changed readily by solvent composition and the addition of guest cations. Especially, disaggregation of the bisfullerene was induced by addition of LiClO4 or NaClO4.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 519-523 |
| ページ数 | 5 |
| ジャーナル | Organic and Biomolecular Chemistry |
| 巻 | 4 |
| 号 | 3 |
| DOI | |
| 出版ステータス | Published - 2006 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学