Coordination assemblies from a Pd(II)-cornered square complex

Makoto Fujita; Masahide Tominaga; Akiko Hori; Bruno Therrien

doi:10.1021/ar040153h

Coordination assemblies from a Pd(II)-cornered square complex

Makoto Fujita, Masahide Tominaga, Akiko Hori, Bruno Therrien

研究成果: Article › 査読

1438 被引用数 (Scopus)

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The [enPd(II)]²⁺ (en = ethylenediamine) unit has emerged as a versatile building block in molecular self-assembly. In particular, the 90° coordination angle of the metal has been judiciously used in the design of new discrete two- and three-dimensional structures. Our last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd₄ square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.

本文言語	English
ページ（範囲）	369-378
ページ数	10
ジャーナル	Accounts of Chemical Research
巻	38
号	4
DOI	https://doi.org/10.1021/ar040153h
出版ステータス	Published - 2005 4月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1021/ar040153h

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AB - The [enPd(II)]2+ (en = ethylenediamine) unit has emerged as a versatile building block in molecular self-assembly. In particular, the 90° coordination angle of the metal has been judiciously used in the design of new discrete two- and three-dimensional structures. Our last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd4 square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.

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Coordination assemblies from a Pd(II)-cornered square complex

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