Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate

Harumi Sakamoto; Yohei Hirohashi; Hisashi Doi; Kazuhiko Noda; Takao Hanawa

Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate

Harumi Sakamoto, Yohei Hirohashi, Hisashi Doi, Kazuhiko Noda, Takao Hanawa

研究成果: Conference contribution

抄録

To create a new material with good biocompatibility and high mechanical strength for artificial organs, titanium (Ti) and segmented polyurethane (SPU) were bonded through 3-(trimethoxysilyl) propyl methacrylate (y-MPS), and specify causes governing the bonding strength of Ti/γ-MPS/SPU interface. The number of cross-links of SPU and the concentration of active hydroxyl groups on the surface oxide film of Ti were controlled by UV-irradaiton and hydrogen peroxide immersion. The number of cross-links of SPU was measured by differential scanning calorimetry (DSC) and the concentration of the active hydroxyl groups was also determined using a zinc-complex substitution technique. Consequently, Ti/y-MPS/SPU shear bonding stress was increased with the increase of the number of cross-links of SPU. In addition, the increase of cross-links in SPU also improved the Ti/y-MPS/SPU shear bonding stress.

本文言語	English
ホスト出版物のタイトル	Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6
ページ	1477-1480
ページ数	4
版	PART 2
出版ステータス	Published - 2007 12月 1
イベント	6th Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6 - Jeju, Korea, Republic of 継続期間: 2007 11月 5 → 2007 11月 9

出版物シリーズ

名前	Materials Science Forum
番号	PART 2
巻	561-565
ISSN（印刷版）	0255-5476

Conference

Conference	6th Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6
国/地域	Korea, Republic of
City	Jeju
Period	07/11/5 → 07/11/9

ASJC Scopus subject areas

材料科学（全般）
凝縮系物理学
材料力学
機械工学

他のファイルとリンク

フィンガープリント

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引用スタイル

Sakamoto, H., Hirohashi, Y., Doi, H., Noda, K., & Hanawa, T. (2007). Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate. In Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6 (PART 2 ed., pp. 1477-1480). (Materials Science Forum; Vol. 561-565, No. PART 2).

Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate. / Sakamoto, Harumi; Hirohashi, Yohei; Doi, Hisashi その他.
Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6. PART 2. ed. 2007. p. 1477-1480 (Materials Science Forum; Vol. 561-565, No. PART 2).

研究成果: Conference contribution

Sakamoto, H, Hirohashi, Y, Doi, H, Noda, K & Hanawa, T 2007, Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate. in Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6. PART 2 edn, Materials Science Forum, no. PART 2, vol. 561-565, pp. 1477-1480, 6th Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6, Jeju, Korea, Republic of, 07/11/5.

Sakamoto H, Hirohashi Y, Doi H, Noda K, Hanawa T. Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate. In Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6. PART 2 ed. 2007. p. 1477-1480. (Materials Science Forum; PART 2).

Sakamoto, Harumi ; Hirohashi, Yohei ; Doi, Hisashi その他. / Effects of cross-linkage and hydroxyl groups on bonding strength between titanium and segmented polyurethane through 3-(trimethoxysilyl) propyl methacrylate. Selected, peer reviewed papers from The Sixth Pacific Rim International Conference on Advanced Materials and Processing, PRICM 6. PART 2. ed. 2007. pp. 1477-1480 (Materials Science Forum; PART 2).

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