Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity

Asao Nakamura; Yoshihisa Inoue

doi:10.1021/ja050704e

Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity

Asao Nakamura, Yoshihisa Inoue

研究成果: Article › 査読

129 被引用数 (Scopus)

抄録

In the enantiodifferentiating supramolecular photocyclodimerization of 2-anthracenecarboxylate using γ-cyclodextrin with a dicationic side chain, a dramatic switching of the product selectivity and a significant enhancement of the enantiomeric excess were achieved by introducing a flexible dicationic sidearm to native γ-cyclodextrin and also by lowering the temperature and solvent polarity.

本文言語	English
ページ（範囲）	5338-5339
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	127
号	15
DOI	https://doi.org/10.1021/ja050704e
出版ステータス	Published - 2005 4月 20

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

文献へのアクセス

10.1021/ja050704e

他のファイルとリンク

フィンガープリント

「Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity. / Nakamura, Asao; Inoue, Yoshihisa.
In: Journal of the American Chemical Society, Vol. 127, No. 15, 20.04.2005, p. 5338-5339.

研究成果: Article › 査読

@article{a21ac49b542541a8bf099a30a06e56de,

title = "Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity",

abstract = "In the enantiodifferentiating supramolecular photocyclodimerization of 2-anthracenecarboxylate using γ-cyclodextrin with a dicationic side chain, a dramatic switching of the product selectivity and a significant enhancement of the enantiomeric excess were achieved by introducing a flexible dicationic sidearm to native γ-cyclodextrin and also by lowering the temperature and solvent polarity.",

author = "Asao Nakamura and Yoshihisa Inoue",

year = "2005",

month = apr,

day = "20",

doi = "10.1021/ja050704e",

language = "English",

volume = "127",

pages = "5338--5339",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Electrostatic manipulation of enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate within γ-cyclodextrin cavity through chemical modification. Inverted product distribution and enhanced enantioselectivity

AU - Nakamura, Asao

AU - Inoue, Yoshihisa

PY - 2005/4/20

Y1 - 2005/4/20

N2 - In the enantiodifferentiating supramolecular photocyclodimerization of 2-anthracenecarboxylate using γ-cyclodextrin with a dicationic side chain, a dramatic switching of the product selectivity and a significant enhancement of the enantiomeric excess were achieved by introducing a flexible dicationic sidearm to native γ-cyclodextrin and also by lowering the temperature and solvent polarity.

AB - In the enantiodifferentiating supramolecular photocyclodimerization of 2-anthracenecarboxylate using γ-cyclodextrin with a dicationic side chain, a dramatic switching of the product selectivity and a significant enhancement of the enantiomeric excess were achieved by introducing a flexible dicationic sidearm to native γ-cyclodextrin and also by lowering the temperature and solvent polarity.

UR - http://www.scopus.com/inward/record.url?scp=17644381893&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=17644381893&partnerID=8YFLogxK

U2 - 10.1021/ja050704e

DO - 10.1021/ja050704e

M3 - Article

C2 - 15826169

AN - SCOPUS:17644381893

SN - 0002-7863

VL - 127

SP - 5338

EP - 5339

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -