Extraction of Pd(ii), Rh(iii) and Ru(iii) from HNO3 aqueous solution to betainium bis(trifluoromethanesulfonyl)imide ionic liquid

Kotoe Sasaki; Koichiro Takao; Tomoya Suzuki; Takahiro Mori; Tsuyoshi Arai; Yasuhisa Ikeda

doi:10.1039/c4dt00091a

Extraction of Pd(ii), Rh(iii) and Ru(iii) from HNO₃ aqueous solution to betainium bis(trifluoromethanesulfonyl)imide ionic liquid

Kotoe Sasaki, Koichiro Takao, Tomoya Suzuki, Takahiro Mori, Tsuyoshi Arai, Yasuhisa Ikeda

研究成果: Article › 査読

63 被引用数 (Scopus)

抄録

Extraction efficiencies of Pd(ii), Rh(iii), and Ru(iii) from HNO ₃(aq) to [Hbet][Tf₂N] were demonstrated, i.e., Pd(ii) is the most extractable, Rh(iii) is medium extractable, and Ru(iii) is the least extractable. The extraction seems to proceed through coordination of betaine to the metal ions and the cation exchange of the formed complex with H⁺.

本文言語	English
ページ（範囲）	5648-5651
ページ数	4
ジャーナル	Dalton Transactions
巻	43
号	15
DOI	https://doi.org/10.1039/c4dt00091a
出版ステータス	Published - 2014 4月 21

ASJC Scopus subject areas

無機化学

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10.1039/c4dt00091a

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引用スタイル

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AU - Suzuki, Tomoya

AU - Mori, Takahiro

AU - Arai, Tsuyoshi

AU - Ikeda, Yasuhisa

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