TY - JOUR
T1 - Mercury-containing transition-metal oxides
T2 - Its high-pressure synthesis and variety of Hg compounds
AU - Yamamoto, Ayako
N1 - Publisher Copyright:
© 2014 Japan Society of High Pressure Science and Technology. All Rights Reserved.
PY - 2014/9/18
Y1 - 2014/9/18
N2 - High-pressure synthesis, crystal structure, and physical properties of mercury-containing transition-metal oxides were introduced from a viewpoint of coordination chemistry of mercury. It is interesting that mercury behaves not only as a cation (Hg2＋) but also as a molecule anion (HgO2 2－) and metal cluster (Hgn). Since mercury is volatile, high-pressure synthesis is an essential technique to produce new mercury-containing compounds.
AB - High-pressure synthesis, crystal structure, and physical properties of mercury-containing transition-metal oxides were introduced from a viewpoint of coordination chemistry of mercury. It is interesting that mercury behaves not only as a cation (Hg2＋) but also as a molecule anion (HgO2 2－) and metal cluster (Hgn). Since mercury is volatile, high-pressure synthesis is an essential technique to produce new mercury-containing compounds.
KW - Cubic anvil press
KW - High-pressure synthesis
KW - Mercury
KW - Metal-insulator transition
KW - Superconductivity
KW - Transition-metal oxides
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U2 - 10.4131/jshpreview.24.188
DO - 10.4131/jshpreview.24.188
M3 - Review article
AN - SCOPUS:84907551839
SN - 0917-639X
VL - 24
SP - 188
EP - 194
JO - Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
JF - Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
IS - 3
ER -