TY - JOUR
T1 - Possible Case of Halogen Bond-Driven Self-Disproportionation of Enantiomers (SDE) via Achiral Chromatography
AU - Terada, Shumpei
AU - Hirai, Motohiro
AU - Honzawa, Ayaka
AU - Kitagawa, Osamu
AU - Kamizela, Angelika
AU - Wzorek, Alicja
AU - Soloshonok, Vadim A.
N1 - Funding Information:
We gratefully acknowledge financial support from JSPS KA-KENNHI No. C 17K08220 (OK), IKERBASQUE, the Basque Foundation for Science (VAS), and from the Ministry of Science and Higher Education Grant No. 612 561 (AW).
PY - 2017/10/17
Y1 - 2017/10/17
N2 - The major breakthrough reported in this work is the discovery of likely halogen bond-driven self-disproportionation of enantiomers (SDE). Taking into account that the halogen-bonding interactions can be rationally designed and can match, or even exceed, the strength of the more familiar hydrogen bond, this discovery clearly opens an unexpected new direction of research in the areas of molecular chirality and the SDE phenomenon.
AB - The major breakthrough reported in this work is the discovery of likely halogen bond-driven self-disproportionation of enantiomers (SDE). Taking into account that the halogen-bonding interactions can be rationally designed and can match, or even exceed, the strength of the more familiar hydrogen bond, this discovery clearly opens an unexpected new direction of research in the areas of molecular chirality and the SDE phenomenon.
KW - axially chiral compounds
KW - enantiomeric purifications
KW - halogen bonding
KW - molecular chirality
KW - self-disproportionation of enantiomers (SDE)
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U2 - 10.1002/chem.201703308
DO - 10.1002/chem.201703308
M3 - Article
C2 - 28783208
AN - SCOPUS:85031505052
SN - 0947-6539
VL - 23
SP - 14631
EP - 14638
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 58
ER -