Single- and double-cations borohydrides for hydrogen storage applications

Shin Ichi Orimo; Yuko Nakamori; Hai Wen Li; Motoaki Matsuo; Toyoto Sato; Nobuko Ohba; Kazutoshi Miwa; Shin Ichi Towata

Single- and double-cations borohydrides for hydrogen storage applications

Shin Ichi Orimo, Yuko Nakamori, Hai Wen Li, Motoaki Matsuo, Toyoto Sato, Nobuko Ohba, Kazutoshi Miwa, Shin Ichi Towata

研究成果: Conference contribution

抄録

The thermal desorption temperature T_d of single-cation borohydrides was found to decrease with increasing the value of the Pauling electronegativity χ_P of the cation (metal). We examined T _d of double-cation borohydrides ZrLi_n-4(BH ₄)_n, and then the correlation between T_d and χ_P determined for single-cation borohydrides is extended to double-cation ones. T_d for ZrLi_n-4(BH₄) _n with the composition n from 4 to 6 continuously increases from 440 K to 650 K, and approaches that of LiBH₄, 740 K: T_d correlates with the averaged χ_P calculated from n. The extended correlation might lead to precise adjustments in the thermodynamical stabilities of borohydrides.

本文言語	English
ホスト出版物のタイトル	Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium
出版社	World Scientific Publishing Co. Pte Ltd
ページ	124-129
ページ数	6
ISBN（印刷版）	9812838015, 9789812838018
出版ステータス	Published - 2009
外部発表	はい
イベント	2007 International Symposium on Materials Issues in a Hydrogen Economy - Richmond, VA, United States 継続期間: 2007 11月 12 → 2007 11月 15

出版物シリーズ

名前	Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium

Conference

Conference	2007 International Symposium on Materials Issues in a Hydrogen Economy
国/地域	United States
City	Richmond, VA
Period	07/11/12 → 07/11/15

ASJC Scopus subject areas

電子材料、光学材料、および磁性材料

他のファイルとリンク

Scopusの出版物のリンク

引用スタイル

Orimo, S. I., Nakamori, Y., Li, H. W., Matsuo, M., Sato, T., Ohba, N., Miwa, K., & Towata, S. I. (2009). Single- and double-cations borohydrides for hydrogen storage applications. In Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium (pp. 124-129). (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium). World Scientific Publishing Co. Pte Ltd.

Single- and double-cations borohydrides for hydrogen storage applications. / Orimo, Shin Ichi; Nakamori, Yuko; Li, Hai Wen その他.

Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. World Scientific Publishing Co. Pte Ltd, 2009. p. 124-129 (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium).

研究成果: Conference contribution

Orimo, SI, Nakamori, Y, Li, HW, Matsuo, M, Sato, T, Ohba, N, Miwa, K & Towata, SI 2009, Single- and double-cations borohydrides for hydrogen storage applications. in Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium, World Scientific Publishing Co. Pte Ltd, pp. 124-129, 2007 International Symposium on Materials Issues in a Hydrogen Economy, Richmond, VA, United States, 07/11/12.

Orimo SI, Nakamori Y, Li HW, Matsuo M, Sato T, Ohba N その他. Single- and double-cations borohydrides for hydrogen storage applications. In Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. World Scientific Publishing Co. Pte Ltd. 2009. p. 124-129. (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium).

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AU - Ohba, Nobuko

AU - Miwa, Kazutoshi

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Single- and double-cations borohydrides for hydrogen storage applications

抄録

出版物シリーズ

Conference

ASJC Scopus subject areas

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