Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid

Toshinari Ogura; Koichiro Takao; Kotoe Sasaki; Tsuyoshi Arai; Yasuhisa Ikeda

doi:10.1021/ic2015989

Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid

Toshinari Ogura, Koichiro Takao, Kotoe Sasaki, Tsuyoshi Arai, Yasuhisa Ikeda

研究成果: Article › 査読

23 被引用数 (Scopus)

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Reduction of U^VIO₂Cl₄^2- in a mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and its chloride at E°′ =-0.996 V vs Fc/Fc⁺ and 298 K affords U ^VO₂Cl₄^3-, which is kinetically stable and exhibits typical character of U^V in the UV-vis-NIR absorption spectrum.

本文言語	English
ページ（範囲）	10525-10527
ページ数	3
ジャーナル	Inorganic Chemistry
巻	50
号	21
DOI	https://doi.org/10.1021/ic2015989
出版ステータス	Published - 2011 11月 7

ASJC Scopus subject areas

物理化学および理論化学
無機化学

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abstract = "Reduction of UVIO2Cl42- in a mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and its chloride at E°′ =-0.996 V vs Fc/Fc+ and 298 K affords U VO2Cl43-, which is kinetically stable and exhibits typical character of UV in the UV-vis-NIR absorption spectrum.",

author = "Toshinari Ogura and Koichiro Takao and Kotoe Sasaki and Tsuyoshi Arai and Yasuhisa Ikeda",

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AU - Arai, Tsuyoshi

AU - Ikeda, Yasuhisa

PY - 2011/11/7

Y1 - 2011/11/7

N2 - Reduction of UVIO2Cl42- in a mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and its chloride at E°′ =-0.996 V vs Fc/Fc+ and 298 K affords U VO2Cl43-, which is kinetically stable and exhibits typical character of UV in the UV-vis-NIR absorption spectrum.

AB - Reduction of UVIO2Cl42- in a mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and its chloride at E°′ =-0.996 V vs Fc/Fc+ and 298 K affords U VO2Cl43-, which is kinetically stable and exhibits typical character of UV in the UV-vis-NIR absorption spectrum.

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Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid

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