Structural properties and thermoelectric performance of the double-filled skutterudite (Sm,Gd)y(FexNi1-x)4Sb12

Cristina Artini, Riccardo Carlini, Roberto Spotorno, Fainan Failamani, Takao Mori, Paolo Mele

研究成果: Article査読

15 被引用数 (Scopus)


The structural and thermoelectric properties of the filled skutterudite (Sm,Gd)y(FexNi1-x)4 Sb12 were investigated and critically compared to the ones in the Sm-containing system with the aim of unravelling the effect of double filling on filling fraction and thermal conductivity. Several samples (x = 0.50-0.90 and y = 0.15-0.48) were prepared by melting-sintering, and two of them were densified by spark plasma sintering in order to study their thermoelectric features. The crystallographic study enables the recognition of the role of the filler size in ruling the filling fraction and the compositional location of the p/n crossover: It has been found that the former lowers and the latter moves toward lower x values with the reduction of the filler ionic size, as a consequence of the progressively weaker interaction of the filler with the Sb12 cavity. The analysis of thermoelectric properties indicates that, despite the Sm3+/Gd3+ small mass difference, the contemporary presence of these ions in the 2a site significantly affects the thermal conductivity of both p- and n-compositions. This occurs by reducing its value with respect to the Sm-filled compound at each temperature considered, and making the overall thermoelectric performance of the system comparable to several multi-filled (Fe, Ni)-based skutterudites described in the literature.

出版ステータスPublished - 2019 8月 1

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学


「Structural properties and thermoelectric performance of the double-filled skutterudite (Sm,Gd)y(FexNi1-x)4Sb12」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。