Synthesis and crystal structures of fluorinated β-diketonate metal (Al3+, Co2+, Ni2+, and Cu2+) complexes

Akiko Hori; Ayaka Shinohe; Shohei Takatani; Takeshi K. Miyamoto

doi:10.1246/bcsj.82.96

Synthesis and crystal structures of fluorinated β-diketonate metal (Al³⁺, Co²⁺, Ni²⁺, and Cu²⁺) complexes

Akiko Hori, Ayaka Shinohe, Shohei Takatani, Takeshi K. Miyamoto

研究成果: Article › 査読

16 被引用数 (Scopus)

抄録

Co²⁺, Ni²⁺, and Cu²⁺ complexes with bis(pentafluorobenzoyl)methanide (L, C₆F₅COCHCOC ₆F₅^-) were prepared from [Al(L)₃], which was directly synthesized from AlCl₃, pentafluorobenzoyl chloride, and vinyl acetate under N₂ atmosphere. The complexation of L with Co²⁺ and Ni²⁺ ions gave [M₂(L) ₄(OH₂)₂] (M = Co and Ni) and that with Cu ²⁺ ion gave [Cu(L)₂].

本文言語	English
ページ（範囲）	96-98
ページ数	3
ジャーナル	Bulletin of the Chemical Society of Japan
巻	82
号	1
DOI	https://doi.org/10.1246/bcsj.82.96
出版ステータス	Published - 2009
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/bcsj.82.96

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引用スタイル

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AU - Miyamoto, Takeshi K.

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N2 - Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5-) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].

AB - Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5-) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].

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