Synthesis of Optically Active Atropisomeric Anilide Derivatives through Diastereoselective N-Allylation with a Chiral Pd-π-Allyl Catalyst

Osamu Kitagawa; Masashi Takahashi; Mitsuteru Kohriyama; Takeo Taguchi

doi:10.1021/jo035305l

Synthesis of Optically Active Atropisomeric Anilide Derivatives through Diastereoselective N-Allylation with a Chiral Pd-π-Allyl Catalyst

Osamu Kitagawa, Masashi Takahashi, Mitsuteru Kohriyama, Takeo Taguchi

研究成果: Article › 査読

10 被引用数 (Scopus)

抄録

N-Allylation of o-tert-butyl anilides derived from o-tert-butyl aniline and (S)-lactic acid or (S)-mandelic acid proceeded with high diastereoselectivity in the presence of a (BINAP)Pd-π-allyl catalyst to give atropisomeric N-allyl o-tert-butyl anilide derivatives.

本文言語	English
ページ（範囲）	9851-9853
ページ数	3
ジャーナル	Journal of Organic Chemistry
巻	68
号	25
DOI	https://doi.org/10.1021/jo035305l
出版ステータス	Published - 2003 12月 12
外部発表	はい

ASJC Scopus subject areas

有機化学

文献へのアクセス

10.1021/jo035305l

他のファイルとリンク

フィンガープリント

「Synthesis of Optically Active Atropisomeric Anilide Derivatives through Diastereoselective N-Allylation with a Chiral Pd-π-Allyl Catalyst」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{caabee008039427295bded8746387b35,

title = "Synthesis of Optically Active Atropisomeric Anilide Derivatives through Diastereoselective N-Allylation with a Chiral Pd-π-Allyl Catalyst",

abstract = "N-Allylation of o-tert-butyl anilides derived from o-tert-butyl aniline and (S)-lactic acid or (S)-mandelic acid proceeded with high diastereoselectivity in the presence of a (BINAP)Pd-π-allyl catalyst to give atropisomeric N-allyl o-tert-butyl anilide derivatives.",

author = "Osamu Kitagawa and Masashi Takahashi and Mitsuteru Kohriyama and Takeo Taguchi",

year = "2003",

month = dec,

day = "12",

doi = "10.1021/jo035305l",

language = "English",

volume = "68",

pages = "9851--9853",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - Synthesis of Optically Active Atropisomeric Anilide Derivatives through Diastereoselective N-Allylation with a Chiral Pd-π-Allyl Catalyst

AU - Kitagawa, Osamu

AU - Takahashi, Masashi

AU - Kohriyama, Mitsuteru

AU - Taguchi, Takeo

PY - 2003/12/12

Y1 - 2003/12/12

N2 - N-Allylation of o-tert-butyl anilides derived from o-tert-butyl aniline and (S)-lactic acid or (S)-mandelic acid proceeded with high diastereoselectivity in the presence of a (BINAP)Pd-π-allyl catalyst to give atropisomeric N-allyl o-tert-butyl anilide derivatives.

AB - N-Allylation of o-tert-butyl anilides derived from o-tert-butyl aniline and (S)-lactic acid or (S)-mandelic acid proceeded with high diastereoselectivity in the presence of a (BINAP)Pd-π-allyl catalyst to give atropisomeric N-allyl o-tert-butyl anilide derivatives.

UR - http://www.scopus.com/inward/record.url?scp=0344666646&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0344666646&partnerID=8YFLogxK

U2 - 10.1021/jo035305l

DO - 10.1021/jo035305l

M3 - Article

C2 - 14656123

AN - SCOPUS:0344666646

SN - 0022-3263

VL - 68

SP - 9851

EP - 9853

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 25

ER -